Del Villar, Ignacio
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Del Villar
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Ignacio
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Ingeniería Eléctrica, Electrónica y de Comunicación
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ISC. Institute of Smart Cities
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Publication Open Access ESA-based in-fiber nanocavity for hydrogen–peroxide detection(IEEE, 2005) Del Villar, Ignacio; Matías Maestro, Ignacio; Arregui San Martín, Francisco Javier; Claus, Richard O.; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Gobierno de Navarra / Nafarroako GobernuaA fiber-optic sensor sensitive to hydrogen peroxide has been designed based on the electrostatic layer-by-layer selfassembly method. Prussian blue has been deposited in a polymeric structure formed by Poly(allylamine hydrochloride) and poly(acrylic acid). The concentration that can be detected range between 10 6–10 3 M, and recovery of the sensor after immersion into a reductive agent was demonstrated. The response of the sensor is independent of thepHfor values that range between 4–7.4. Some rules for estimation of the refractive index of the material deposited and the thickness of the bilayers are also presentedPublication Open Access Strategies for fabrication of hydrogen peroxide sensors based on electrostatic self-assembly (ESA) method(Elsevier, 2004) Del Villar, Ignacio; Matías Maestro, Ignacio; Arregui San Martín, Francisco Javier; Echeverría Morrás, Jesús; Claus, Richard O.; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Gobierno de Navarra / Nafarroako GobernuaAn optical fiber sensor has been fabricated for detection of 5 M–0.1mM concentrations of hydrogen peroxide with a linear response. The deposition method used is electrostatic self-assembly (ESA) of polymer cationic and anionic layers. Prussian Blue (PB) has been included in the polycation layers. The optical fiber sensor is included in a reflection setup, where the measuring technique is based on the slope of the optical reflected power change caused by oxidation of Prussian White (PW) to Prussian Blue. The sensor recovers after immersion in a reductive agent and is immune against a variety of components. Measurement of hydrogen peroxide has been proved successfully in a wide range pHs between 3 and 9. Some techniques have been applied in order to avoid the lost of indicator.