Open Access
Dielectric sensing of deeply subwavelength analytes using epsilon-near-zero waveguides
(IEEE, 2024-10-08) Lezaun Capdevila, Carlos; Pacheco-Peña, Víctor; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC
The advent of metamaterials brought new wave-matter interaction paradigms to manipulate field and waves at will. Their applications are numerous: antennas, lenses, invisibility cloaking, computing, vortex beams and more. In turn, epsilon-near-zero (ENZ) metamaterials opened up new phenomena for light manipulation due to their exotic propagation constant, wavenumber and characteristic impedance. In 2008, it was demonstrated that a rectangular waveguide can emulate ENZ media by working near the cutoff frequency [1]. Moreover, the incredible field confinement inside the ENZ waveguide provided interesting features for sensing applications [2]. Our work further develops the idea of a dielectric body sensor based on a ENZ waveguide by considering an analyte partially filling the waveguide [3] and demonstrating empirically the setup [4].
Open Access
Towards cooling concrete: evaluation of cement and cement composites under realistic climatic conditions
(Elsevier, 2025-04-15) Torres García, Alicia E.; Agbaoye, Ridwan O.; Carlosena Remírez, Laura; Goracci, Guido; Lezaun Capdevila, Carlos; Dolado, Jorge S.; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Ingeniería; Ingeniaritza
Finding scalable, cost-effective and environmentally safe solutions for Passive Daytime Radiative Cooling (PDRC) is essential for addressing energy and climate challenges. This study demonstrates the feasibility of achieving PDRC using only cement-based compounds, without the need for additional whitening agents or other additives. Unlike previous approaches that rely on external additives, the proposed solution leverages two fundamental cement phases—portlandite and tobermorite—offering a scalable and low-impact alternative. The research evaluates the radiative cooling potential of these phases, along with two widely used cements—white cement (WC) and ordinary Portland cement (OPC), by analyzing and comparing their homogenized complex permittivities, derived using the Kramers-Kronig (KK) method. Simulations were conducted to assess the cooling power over one year across three different climates using actual meteorological data. The portlandite exhibits positive Pcool, maintaining a temperature equal to or below the ambient temperature more than 90 % of the time in dry desert and warm temperate locations. Indoor controlled measurements results reveal that portlandite (CH) may exhibit temperatures 15 °C lower than OPC and 5 °C lower than WC.
Open Access
Perfect narrowband absorbers using simple lithography-free structures
(IEEE, 2024-10-08) Lezaun Capdevila, Carlos; Navajas Hernández, David; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC
Light absorption is a key phenomenon for a variety of technologies [1]: radiative cooling, photovoltaics, sensing, communication and camouflaging are just a few examples. These applications demand scalable and compact devices that modulate their absorption spectra, usually engineered using cavities and/or periodic structures acting as resonators. Weak light matter interaction limits the absorption within ultra-compact devices, although epsilon-near-zero (ENZ) materials allows to greatly increase such interaction [2]. The lack of design standardization presents a big gap for designing absorbers. We present a thorough analysis of an arbitrary material on top of a PEC (perfect electric reflector) and a material separated by a spacer from the PEC. We overview the absorption phenomena for different permittivity regions, thicknesses, angles of incidence and polarization. This work helps standardize the design of these absorber configuration.
Open Access
Design of multi-layered radiative cooling structures using evolutionary algorithms
(IEEE, 2022) Lezaun Capdevila, Carlos; Jorajuria Gómez, Tania; Torres García, Alicia E.; Herrera, Pilar; Beruete Díaz, Miguel; Institute of Smart Cities - ISC; Ingeniería Eléctrica y Electrónica; Ingeniaritza Elektrikoa eta Elektronikoa; Gobierno de Navarra / Nafarroako Gobernua
In this work we present a novel way to design thinfilm radiative cooling metamaterials based on genetic algorithms. Three simulations with different design constraints have been done, resulting in three structures that achieve 39.96 W/m2 , 57.78 W/m2 and 61.77 W/m2 under direct sunlight, respectively. These structures are shorter than 5 µm of height and are composed of 9, 15 and 24 layers. This design method has the advantages of being automatable, needs fewer design experience in metamaterials and does not rely on commercial simulators. This work opens the path to an easy way of automated design of thin-film multi-layered devices for radiative cooling and other applications in the infrared range.
Open Access
Suppressed-scattering spectral windows for radiative cooling applications
(Optica, 2023) Pérez Escudero, José Manuel; Torres García, Alicia E.; Lezaun Capdevila, Carlos; Caggiano, Antonio; Peralta, Ignacio; Dolado, Jorge S.; Beruete Díaz, Miguel; Liberal Olleta, Íñigo; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
The scattering of light by resonant nanoparticles is a key process for enhancing the solar reflectance in daylight radiative cooling. Here, we investigate the impact of material dispersion on the scattering performance of popular nanoparticles for radiative cooling applications. We show that, due to material dispersion, nanoparticles with a qualitatively similar response at visible frequencies exhibit fundamentally different scattering properties at infrared frequencies. It is found that dispersive nanoparticles exhibit suppressed-scattering windows, allowing for selective thermal emission within a highly reflective sample. The existence of suppressed-scattering windows solely depends on material dispersion, and they appear pinned to the same wavelength even in random composite materials and periodic metasurfaces. Finally, we investigate calcium-silicate-hydrate (CSH), the main phase of concrete, as an example of a dispersive host, illustrating that the co-design of nanoparticles and host allows for tuning of the suppressed-scattering windows. Our results indicate that controlled nanoporosities would enable concrete with daylight passive radiative cooling capabilities.
Open Access
Nanoparticle derived suppressed-scattering bands for radiative cooling
(IEEE, 2023) Lezaun Capdevila, Carlos; Pérez Escudero, José Manuel; Torres García, Alicia E.; Caggiano, Antonio; Peralta, Ignacio; Dolado, Jorge S.; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC
Light scattering using resonant nanoparticles is crucial for improving sun irradiance reflection in a daytime radiative cooler. Popular nanoparticles in radiative cooling literature are analyzed in terms of scattering performance due to material dispersion. Different scattering properties in the infrared range have been detected while a similar behavior can be achieved in the solar range due to changes in material dispersion. Also, suppressed scattering windows are produced by dispersive nanoparticles, allowing high reflectance while enabling thermal emission selectively. Material dispersion alone produces such scattering windows, thus, given a material, they will always remain in the same region regardless geometry and location of particles. Lastly, calcium silicate hydrate (CSH), the main phase of concrete, is studied as a dispersive host example. These results demonstrate the importance of a co-design between host and nanoparticles dispersion for daytime radiative cooling and that nanoporosities design are a key ingredient that could allow concrete-based daytime radiative coolers.
Open Access
Multiple absorption regimes in simple lithography-free structures leading to ultrathin slabs
(2024-07-08) Lezaun Capdevila, Carlos; Navajas Hernández, David; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC; Universidad Pública de Navarra / Nafarroako Unibertsitate Publikoa
Electromagnetic absorbers serve as fundamental components for a wide range of applications, encompassing energy and heat management, sensing, and communications. In this study, we explore several complex permittivity combinations for lithography-free material-reflector and material-spacer-reflector configurations that lead to perfect absorption peaks across distinct permittivity regimes and varying thicknesses. We provide an extensive analysis of angle and polarization dependencies, specifically using silicon carbide as an illustrative example. Our findings reveal the potential for harnessing different absorption regimes within a single device, thus enabling the realization of multiband absorption capabilities. Furthermore, we demonstrate perfect absorption linked with extreme values of permittivity, and we find the conditions to get perfect absorption in ultrathin slabs. In addition, we carry out an analysis about the response at oblique incidence, and we identify a particular mode in the negative permittivity region and its hybridization with epsilon-near-zero modes at oblique incidence. This investigation serves as a valuable standardization of absorber design, offering insights to develop perfect absorbers for infrared applications such as thermal emission, communications, and sensing.
Open Access
Enhancing the infrared and visible emission properties of calcium silicate hydrate for radiative cooling using metamaterials
(IEEE, 2022) Lezaun Capdevila, Carlos; Dolado, Jorge S.; Torres García, Alicia E.; Pérez Escudero, José Manuel; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
Two periodic structures composed of metal cylinders with different orientations are used to improve the solar reflection of calcium silicate hydrate (CSH) while maintaining its atmospheric emission. Interesting effects have been found when the distance between bars is small, suggesting that lattice effects, arising from the interaction between the rods could be leveraged in the design of these metamaterials. The size of the metal bars is selected based on state of the art micro-manufacturing techniques. This study limits its scope to a CSH gel model; i.e. the most important component of cement-based materials. Further research will be undertaken to consider a best description of the dielectric function of concrete.
Open Access
Evolutionary algorithms applied to multi-layered radiative cooling metamaterials
(IEEE, 2022) Lezaun Capdevila, Carlos; Jorajuria Gómez, Tania; Torres García, Alicia E.; Herrera, Pilar; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Institute of Smart Cities - ISC; Ingeniaritza Elektrikoa, Elektronikoaren eta Telekomunikazio Ingeniaritzaren
A newly design method for designing multi-layered radiative cooling metamaterials based on genetic algorithms (GAs) is exposed. The developed GA has been tested in three cases, resulting in three different structures that achieve, theoretically under direct sunlight, a net cooling power of 39.96 W/m 2 , 57.78 W/m 2 and 61.77 W/m 2 . Such devices are composed of 9, 15 and 24 layers respectively with a total thickness of less than 4.8 µm in the worst case. By the nature of the method, fewer design experience in metamaterials is needed, as well as it is free-cost, due to the use of analytical calculations for the emissivity of the meta materials instead of a commercial generic electromagnetic solver. Automated design of radiative cooling multi-layered structures and other applications in the infrared range can be further developed with this work.
Open Access
Lithography-free perfect narrowband absorbers using simple layered structures
(IEEE, 2024-10-08) Lezaun Capdevila, Carlos; Navajas Hernández, David; Liberal Olleta, Íñigo; Beruete Díaz, Miguel; Ingeniería Eléctrica, Electrónica y de Comunicación; Ingeniaritza Elektrikoa, Elektronikoa eta Telekomunikazio Ingeniaritza; Institute of Smart Cities - ISC
Light absorbers are key components for multiple applications ranging from heat and energy management to communications and sensing. This work explores different complex permittivity combinations for material-reflector and material-spacer-reflector configurations, achieving perfect absorption under different permittivity regimes and thicknesses. Using silicon carbide, we discuss polarization and angle dependencies, and the potential of exploiting different permittivity regimes within a device for multi-band absorption. This work helps standardize absorber design and offer insights to engineer perfect absorbers for applications such as thermal emission, absorption, communication and sensing.